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Those That Remain Caught in the “Organic Matter Trap”: Sorption/Desorption Study for Levelling the Fate of Selected Neonicotinoids
International Journal of Molecular Sciences, 25 (2024), 11; 5700. https://doi.org/10.3390/ijms25115700
Sinčić Modrić, Gordana; Marinić, Jelena; Karleuša, Romano; Dubrović, Igor; Kosobucki, Przemysław; Broznić, Dalibor

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Sinčić Modrić, G., Marinić, J., Karleuša, R., Dubrović, I., Kosobucki, P. i Broznić, D. (2024). Those That Remain Caught in the “Organic Matter Trap”: Sorption/Desorption Study for Levelling the Fate of Selected Neonicotinoids. International Journal of Molecular Sciences, 25. (11). doi: 10.3390/ijms25115700

Sinčić Modrić, Gordana, et al. "Those That Remain Caught in the “Organic Matter Trap”: Sorption/Desorption Study for Levelling the Fate of Selected Neonicotinoids." International Journal of Molecular Sciences, vol. 25, br. 11, 2024. https://doi.org/10.3390/ijms25115700

Sinčić Modrić, Gordana, Jelena Marinić, Romano Karleuša, Igor Dubrović, Przemysław Kosobucki i Dalibor Broznić. "Those That Remain Caught in the “Organic Matter Trap”: Sorption/Desorption Study for Levelling the Fate of Selected Neonicotinoids." International Journal of Molecular Sciences 25, br. 11 (2024). https://doi.org/10.3390/ijms25115700

Sinčić Modrić, G., et al. (2024) 'Those That Remain Caught in the “Organic Matter Trap”: Sorption/Desorption Study for Levelling the Fate of Selected Neonicotinoids', International Journal of Molecular Sciences, 25(11). doi: 10.3390/ijms25115700

Sinčić Modrić G, Marinić J, Karleuša R, Dubrović I, Kosobucki P, Broznić D. Those That Remain Caught in the “Organic Matter Trap”: Sorption/Desorption Study for Levelling the Fate of Selected Neonicotinoids. International Journal of Molecular Sciences [Internet]. 23.05.2024. [pristupljeno 14.11.2024.];25(11). doi: 10.3390/ijms25115700

G. Sinčić Modrić, J. Marinić, R. Karleuša, I. Dubrović, P. Kosobucki i D. Broznić, "Those That Remain Caught in the “Organic Matter Trap”: Sorption/Desorption Study for Levelling the Fate of Selected Neonicotinoids", International Journal of Molecular Sciences, vol. 25, br. 11, Svibanj 2024. [Online]. Dostupno na: https://urn.nsk.hr/urn:nbn:hr:184:160810. [Citirano: 14.11.2024.]

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Podaci o radu
Naslov (engleski)Those That Remain Caught in the “Organic Matter Trap”: Sorption/Desorption Study for Levelling the Fate of Selected Neonicotinoids
AutorGordana Sinčić Modrić
AutorJelena Marinić
AutorRomano Karleuša
AutorIgor Dubrović
AutorPrzemysław Kosobucki
AutorDalibor Broznić
Autorova ustanovaSveučilište u Rijeci
Medicinski fakultet
(Katedra za medicinsku kemiju, biokemiju i kliničku kemiju)
Znanstveno / umjetničko
područje, polje i grana		BIOMEDICINA I ZDRAVSTVO
Javno zdravstvo i zdravstvena zaštita
Sažetak (engleski)
With projections suggesting an increase in the global use of neonicotinoids, contemporary farmers can get caught on the “pesticide treadmill”, thus creating ecosystem side effects. The aim of this study was to investigate the sorption/desorption behavior of acetamiprid, imidacloprid, and thiacloprid that controls their availability to other fate-determining processes and thus could be useful in leveling the risk these insecticides or their structural analogues pose to the environment, animals, and human health. Sorption/desorption isotherms in four soils with different organic matter (OC) content were modelled by nonlinear equilibrium models: Freundlich’s, Langmuir’s, and Temkin’s. Sorption/desorption parameters obtained by Freundlich’s model were correlated to soil physico-chemical characteristics. Even though the OC content had the dominant role in the sorption of the three insecticides, the role of its nature as well as the chemical structure of neonicotinoids cannot be discarded. Insecticides sorbed in the glassy OC phase will be poorly available unlike those in the rubbery regions. Imidacloprid will fill the sorption sites equally in the rubbery and glassy phases irrespective of its concentration. The sorption of thiacloprid at low concentrations and acetamiprid at high concentrations is controlled by hydrophilic aromatic structures, “trapping” the insecticides in the pores of the glassy phase of OC.
Ključne riječi (engleski)
Jezikengleski
Vrsta publikacijeZnanstveni rad - Izvorni znanstveni rad
Status objaveObjavljen
Vrsta recenzijeRecenziran - međunarodna recenzija
Verzija publikacijeObjavljena verzija rada (izdavačev PDF)
Naslov časopisaInternational Journal of Molecular Sciences
Brojčani podacivol. 25, br. 11, 5700
e-ISSN1422-0067
DOIhttps://doi.org/10.3390/ijms25115700
URN:NBNurn:nbn:hr:184:160810
Datum objave publikacije2024-05-23
URL dokumentahttps://www.mdpi.com/1422-0067/25/11/5700
Vrsta resursaTekst
Prava pristupaOtvoreni pristup
Uvjeti korištenjaIkona licence Imenovanje 4.0 međunarodna (CC BY 4.0)
Datum i vrijeme pohrane2024-05-27 09:43:54